1,2-Bis[bis(methylsulfanyl)methylene]hydrazine
نویسندگان
چکیده
The title compound, C(6)H(12)N(2)S(4), was obtained as a by-product (8%) during the reaction of the electrogenerated cyano-methyl anion with phenyl-amine, carbon disulfide and methyl iodide. The mol-ecule, with the exception of 8 H atoms, lies on a crystallographic mirror plane and is arranged around an inversion centre located at the mid-point of the N-N bond.
منابع مشابه
1,2-Bis[amino(pyrimidin-2-yl)methylene]hydrazine dihydrate
The centrosymmetric organic molecule in the title compound, C(10)H(10)N(8)·2H(2)O, is essentially flat and has a trans configuration. The mol-ecules are linked by inter-molecular O-H⋯N, N-H⋯O and N-H⋯N hydrogen bonds to form a linear chain structure.
متن کامل1,2-Bis{4-[1-(anthracen-9-ylmethyl)-1H-1,2,3-triazol-4-yl]phenyl}-1,2-bis[4,5-bis(methylsulfanyl)-1,3-dithiol-2-ylidene]ethane
The title mol-ecule, C58H44N6S8, has point symmetry 2 (in the Schönfliess notation C2). The related crystallographic twofold axis bis-ects the central ethane bond while it is parallel to the monoclinic unique axis of the unit cell. The dithiole=C-C=dithiole torsion angle is 103.7 (4)° and the triazole-anthracene moieties adopt a pincer-like conformation. The crystal structure features C-H⋯S and...
متن کاملcatena-Poly[[[bis(O,O′-diisobutyl dithiophosphato-κ2 S,S′)nickel(II)]-μ-1,2-bis(4-pyridylmethylene)hydrazine-κ2 N:N′] toluene disolvate]
The polymeric title compound, {[Ni(C(8)H(18)O(2)PS(2))(2)(C(12)H(10)N(4))]·2C(7)H(7)}(n), has a linear topology and features octa-hedrally coordinated Ni atoms with a trans-N(2)S(4) donor set. The toluene solvent mol-ecules occupy channels defined by the three-dimensional stacking of the polymeric chains. The Ni atom is located at a centre of inversion and the bridging 1,2-bis-(4-pyridylmethyl-...
متن کاملDi-tert-butyl 1-[2-hydroxy-3-(methylsulfanyl)propyl]hydrazine-1,2-dicarboxylate
The title compound, C14H28N2O5S, was synthesized by the reaction of 2-[(methyl-sulfan-yl)meth-yl]oxirane with di-tert-butyl oxalate in hydrazine hydrate. In the crystal, mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds into supra-molecular chains propagating along the b-axis direction.
متن کامل[μ-N 1,N 2-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)]
The binuclear title compound, [Cu2(C12H10N6S2)Cl2], possesses twofold rotational symmetry. The Cu(II) atom occupies a four-coordinate pseudo-tetra-hedral environment bound to one S atom, one imine N atom and one pyridine N atom from the N(1),N(2)-bis-(pyridin-2-yl)hydrazine-1,2-dicarbo-thio-amidate ligand, and one Cl(-) anion. The metal atoms are connected via the bis-tridentate ligand into a b...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008